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3 ways to exploit the large surface area of microfibrillated cellulose

Posted by Anni Karppinen 31. May 2016

large_surface_area_of_mfc-036020-edited.jpgOne of the benefits of microfibrillated cellulose (MFC) is its very high surface area. It is considerably higher than the surface area of many traditional cellulose materials, like cellulose fibers used in paper making or microcrystalline cellulose. When the fibers are torn down to smaller and smaller fibrils, the surface area consequently increases, which leads to new properties and applications. Let’s have a look at some examples of these applications.

1. Longer wet edge and open time for coatings

The large surface area of MFC can bind a lot of water molecules on the fibers. This leads to a good water holding capacity which is a useful property in different products.

For instance, it can be utilized in wood coatings where MFC prolongs the wet edge and open time of the coating. The open time means the period of time when irregularities on the fresh coating layer can be repaired without brush marks. Wet edge time is related to the same properties of the coating and means the time period when a new layer of the coating can be applied without causing lap marks.

These properties can be improved if the outmost layer of the coating remains wet longer. Figure 1 shows how MFC improves the wet edge time which is related to its water holding capacity. When the time window for applying the second layer, or correcting any marks on the surface increase, the application of the coating becomes more flexible and easier.

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Figure: The wood pieces are coated with a reference wood coating and a wood coating containing MFC (Borregaard’s Exilva). The application of the coating is made differently in different parts: A) 2 layers of the coating, 10 min between the application; B) 1 coating layer; C) 2 layers of the coating, 5 min between the application. The wood coating with MFC has smoother appearance between the different application methods, showing that the wet edge time is longer.

2. Composite materials for food packaging

The large surface area means that the MFC fibers have a lot of opportunities to interact with surrounding components and materials, also other than water. This is beneficial in composite materials, where a strong adhesion between the reinforcing fibers and surrounding matrix is essential for the strength properties.

In addition, when the fibers are long and thin, the so-called percolation threshold is lower than for macro-sized fibers. Percolation threshold is the lowest mass percentage of fibers that gives a continuous network of fibers and, in that way, a mechanically strong composite. Large surface area makes it possible to prepare stronger composites with a low amount of fibers.

Food packages are an example of composites where MFC could be used. In addition to mechanical strength, a MFC film is a good oxygen barrier and suitable for multilayer films. However, its oxygen barrier properties are reduced in humid conditions.

The MFC surface is hydrophilic, meaning that it likes polar compounds like water. This is probably the explanation why MFC loses its oxygen barrier properties in humid conditions: The water molecules get in between the fibers and make the network swollen and looser. The swelling can be reduced by surface modifications which make the fibers more hydrophobic either by physical (adsorption) or chemical modifications. More information on this topic can be found, for instance, in a review by Nair et al. 2014 and PFI’s Newsletter.

3. Carrier in biomedical applications

MFC, with its large surface area, could also be used in biotechnology; as a carrier for enzymes and proteins, carrier in controlled drug release or in scaffolds for cellular culture.

Proteins and enzymes can be used in antibody-based diagnostic, but they are quite sensitive materials, which means they need a carrier to protect them. By trapping the proteins within the porous network, absorbing them or binding covalently on the surface, MFC can act as a carrier and increase the stability in operation and storage.To get a good binding between the protein or enzyme and MFC, suitable surface modification is needed.

In similar way, MFC could stabilize drug formulation and, when placed in the human body, release the drug molecules in a controlled way.

A slightly different biomedical application is scaffolds for growing cells which are needed, for instance, to grow new bone tissue after a serious injury. MFC offers mechanical support to the cell growth, and other necessary substances can be adsorbed on the fibers surface.

In general, MFC is a good candidate to be used in human body since cellulose is biocompatible, although not readily degraded by the human body. Lin and Dufresne (2014) have written an interesting review about biomedical applications of MFC and other nanocellulose materials.

Large surface area – a lot of interactions

Above, I have listed examples of how to benefit from MFC’s large surface area. Basically, when the material has a large surface area, it interacts more strongly with the surroundings. It means that the material can, for example, adsorb more molecules or have stronger interactions with other substances around it.

This together with MFC’s good mechanical properties and non-toxicity makes it an attractive material for many purposes.

 

 

Free eBook for download: Microfibrillated Cellulose at a Glance

 

Topics: MFC


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By: Anni Karppinen

Anni has worked with MFC since 2008, first at the Aalto University and the last two years at Borregaard as a research scientist. In her current work, she concentrates on the analysis of MFC and different technical applications. Her main interest lies in the flow properties and rheology of MFC. Anni has a doctoral degree in Polymer Technology.

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Exilva is Borregaard’s innovative new additive within the field of Cellulose fibrils / Microfibrillated cellulose (MFC). Exilva is a completely natural and infinitely sustainable performance enhancer that improves rheology and stability in product formulations.


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